Swati Ravi, Lorenzo Marra, James F. Steiner, Guglielmo Mastroserio, Mason Ng, Joey Neilsen, Herman L. Marshall, Fiamma Capitanio, Sudeb Ranjan Datta, Elise Egron, Javier A. Garcia, Adam Ingram, Philip Kaaret, Ole Koenig, Honghui Liu, Romana Mikusincova, Edward J. R. Nathan, P. -O. Petrucci, Jakub Podgorny, Chiara Salvaggio, Jiri Svoboda, Alexandra Veledina, Yuexin Zhang

We report the discovery of significant X-ray polarization from the dynamically confirmed black hole X-ray binary (BHXB) GS 1354-64 during its 2025-2026 outburst, obtained with the Imaging X-ray Polarimetry Explorer (IXPE). The observation, obtained shortly after a bright X-ray flare, captures the source in an intermediate state following a stalled (failed) state transition. We discover significant 2-8 keV polarization at the ~4% level with high statistical support--14-sigma significance from frequentist analysis and log Bayes Factor 283+/-1 in a Bayesian framework--measuring PD 4.0+/-0.2% and PA-1+/-2 degrees (90% credible interval). The PD exhibits a statistically significant increasing trend with energy--the strongest such increase yet observed by IXPE in a BHXB--going from 2.1+/-0.3% in the 2-3 keV band to 11+/-3% in the 6.5-7 keV band, while the PA appears stable across both energy and time to within statistical uncertainties. Timing analysis of the IXPE data reveals a ~5 Hz Type-C quasi-periodic oscillation. IXPE + NuSTAR spectropolarimetric modeling suggests that the data can be described by polarized thermal disk and Comptonized components with PAs differing by ~90 degrees, or by a dominant Comptonized polarized component whose effective PD increases across the IXPE bandpass--the inferred component-level polarization levels are therefore model-dependent. In either picture, GS 1354-64 retains a strong coronal component during the transitional period observed by IXPE. These results illustrate how X-ray polarimetry can provide a sensitive diagnostic of the accretion state and geometry in black hole X-ray binary accretion flows, exploring a liminal phase at the cusp of state transition.